In order to explore ways to promote college students’access to entrepreneurial resources，based on related theories of entrepreneurship learning and legitimacy，this paper constructs a model of the relationship among college student entrepreneurial network learning，legitimacy， and resource acquisition. Through the empirical analysis based on questionnaire data，the following conclusions are drawn： Entrepreneurial network learning of college students can positively influence the acquisition of entrepreneurial resources；College students’entrepreneurial network learning can have a positive and significant impact on legitimacy； Legitimacy can significantly enhance the ability of college students to acquire entrepreneurial resources； Legitimacy can play a mediating role between college students’entrepreneurial network learning and access to entrepreneurial resources.