Taking A-share listed companies in China from 2007 to 2017 as sample, this paper empirically tests the effects of enterprise risk-taking behavior on auditors’ decision of audit fees. The results indicate that: (1) The higher the level of enterprise risk-taking, the higher the level of audit fees; (2) Compared with small-scale accounting firms, large-scale accounting firms charge higher audit fees for enterprise risk-taking; (3) Compared with private enterprises, accounting firms charge lower audit fees for the risk-taking behavior of state-owned enterprises. Further studies show that: (1) Accounting firms charge higher level of audit fees for risk-taking of enterprises located in areas with better legal environments, which has a regulatory role. In other words, the better the legal environments, the higher fees auditors charge for enterprise risk-taking; (2) While charging a higher audit fees for enterprise risk-taking, the auditors accordingly input higher audit resource, resulting in the lower audit risk.